Phase 2012
1. Synthesis
of new conjugated polymer structures.
2. Synthesis and characterization of star and dendrimer oligomers.
3. New acceptor compounds.
2. Synthesis and characterization of star and dendrimer oligomers.
3. New acceptor compounds.
Phase 2013
1. Synthesis and characterization of new conjugated oligomers and polymers with donor groups.
1.a. Polyarylene vinylene and polyarylene ethynylene containing 2,6- and 3,6-carbazolediyl units. A comparative optoelectronic study. Characterization of polymers by FTIR, NMR, optical properties (UV-vis and fluorescence) electronic structure (HOMO and LUMO levels) (by electrochemistry).
1.b. Modification of polymers and oligomers containing arylene ethynylene groups with strong acceptors.
1.c. Oligomers with acceptor properties.
2. Synthesis of photoactive films of conjugated oligomers and polymers with donor groups and small molecular acceptors. Morphological study of composite films deposited by different techniques. Photoelectrical properties of composite films.
2.a. Star oligomer.
2.b. Arylene vinylene polymers containing 3,6- and 2,7-carbazolyldiyl groups.
1.a. Polyarylene vinylene and polyarylene ethynylene containing 2,6- and 3,6-carbazolediyl units. A comparative optoelectronic study. Characterization of polymers by FTIR, NMR, optical properties (UV-vis and fluorescence) electronic structure (HOMO and LUMO levels) (by electrochemistry).
1.b. Modification of polymers and oligomers containing arylene ethynylene groups with strong acceptors.
1.c. Oligomers with acceptor properties.
2. Synthesis of photoactive films of conjugated oligomers and polymers with donor groups and small molecular acceptors. Morphological study of composite films deposited by different techniques. Photoelectrical properties of composite films.
2.a. Star oligomer.
2.b. Arylene vinylene polymers containing 3,6- and 2,7-carbazolyldiyl groups.
Phase 2014
1. Synthesis and characterization of new conjugated oligomers and polymers with donor groups.
1.1. New oligomers and polymers based on triphenylamine and indolocarbazole.
1.2. Structural characterization of polymers by IR and NMR spectroscopy, optical properties, electronic structure (HOMO and LUMO levels, by electrochemical method).
2. Synthesis of photoactive polymer films from donor polymers and acceptor.
2.1. Morphological studies of the films.
1.1. New oligomers and polymers based on triphenylamine and indolocarbazole.
1.2. Structural characterization of polymers by IR and NMR spectroscopy, optical properties, electronic structure (HOMO and LUMO levels, by electrochemical method).
2. Synthesis of photoactive polymer films from donor polymers and acceptor.
2.1. Morphological studies of the films.
PHASE 2015
1. New acceptor compounds, as substitutes fullerene.
1.1. Studies of new acceptors :graphene oxide, graphene, perylenediimide, etc.
1.2. Structural characterization of acceptors.
1. New acceptor compounds, as substitutes fullerene.
1.1. Studies of new acceptors :graphene oxide, graphene, perylenediimide, etc.
1.2. Structural characterization of acceptors.
PHASE 2016
1. Synthesis of photoactive layers from donor oligomers and polymers and acceptors
1.1. Study of photoelectric properties of composite films
1. Synthesis of photoactive layers from donor oligomers and polymers and acceptors
1.1. Study of photoelectric properties of composite films
